Two questions:
To use intellisense in VS 2010 you need to reffer which files should be loaded for intelli sense. You can archive this with references in the docs where you want to use intelli sense:
/// <reference path="ScriptFile1.js" />
/// <reference path="Scripts/ScriptFile2.js" />
/// <reference path="../ScriptFile3.js" />
/// <reference path="~/Scripts/ScriptFile4.js" />
for more information on intellisense take a look at the MSDN
For the tools part;
Edit
To Update on highlighting, braces, aso :
Javascript tools is a great package directly by Microsoft
editend
Javasript Parser does a great work for me when writing
For testing & Debugging Firebug is the best you get in my opinion, but you can also use the IE developer tools(install only required for older IE, prior 8 if I am not mistaking) for debugging.
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