I just installed the python-mode in Emacs and it seems to be working well. However, I could not find documentation for the package on the official site.
The package comes with a doc folder where I can see two files:
commands-python-mode.org
commands-python-mode.rst
Both files seem to be formatted for some external tool that displays the help text.
With this:
Start off with M-x describe-mode. This gives you an overview over the available key bindings. For each command use C-f name RET to see the built-in documentation. The .org file should be an org-mode file and easily readable with Emacs.
See also here
A cursory inspection of those two files and the code tells me that they're basically a listing of the docstrings found in pymacs.el and python-mode.el. That means you'll be able to access the relevant documentation through M-x apropos or C-h a and friends (specifically, search for ^py or ^pymacs to get a listing of the mode functions). 
As a general rule, because elisp doesn't support namespaces, all functions/variables defined by a given mode will have a consistent prefix related to the name of the mode. That makes it fairly simple to search through the Emacs documentation.
If your a emacs user and haven't heard of org-mode before your in for treat. 
Open the .org file in emacs and go to org-mode (METAxorg-mode), use TAB on the header lines. Header-lines starts with one or more *.
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