I have a NodeJS code that uses https module as: https.request(options, (res) => {...... where options is an object like
const options = {
    hostname: SERVICE_HOSTNAME,
    path: BASE_PATH,
    method: 'GET',
    headers: {
        'Content-Type': 'application/json',
        'Accept': 'application/json',
        ApplicationId,
        Authorization
    }
  };
My problems start when I add Accept header. I getting an error:
TypeError [ERR_INVALID_HTTP_TOKEN]: Header name must be a valid HTTP token ["Accept"]
    at ClientRequest.setHeader (_http_outgoing.js:472:3)
    at new ClientRequest (_http_client.js:203:14)
    at Object.request (https.js:289:10)
How Accept header would be invalid?
Now this is crazy, but you have an extra character in your "Accept" string. If you run
console.log('Accept'.charCodeAt(6)) // prints 8203
(You have to run it with your copy of "Accept" from your question, which I assume is copy-pasted from elsewhere)
Unicode 8203 is zero width space, hence it's not visible to us humans :)
By the way, initially i've discovered the character by copy-pasting into Node REPL and noticing a "square" in console output after getting the error.
I've then tried copy-pasting your code into my IntelliJ editor, and was pleasantly surprised to see this warning:

hlfrmn already found this tricky error and gave the correct answer, just in case anyone else is interested:
Starting from version 14.3.0 Node's http module will perform validateHeaderName and validateHeaderValue on each Key-Value pair you specify in your request options headers.
So if you do
const {validateHeaderName} = require('http');
try {
    const options = {
        method: 'GET',
        headers: {
            'Content-Type': 'application/json',
            'Accept': 'application/json',
        }
    };
    for (const header in options.headers) {
        validateHeaderName(header);
    }
} catch (err) {
    console.log(err);
}
the mentioned error will be printed:
TypeError [ERR_INVALID_HTTP_TOKEN]: Header name must be a valid HTTP token ["Accept"] will be printed from the catch block.
                        I didn't eat because of your question T_T
As @hlfrmn said, you have a rare char in your Accept word!!
I reproduced the error:
const https = require('https');
//copied from origin question
var copiedOptions = {
  headers: {
    'Content-Type': 'application/json',
    "Accept": 'application/json'
  }
}
var writedOptions = {
  headers: {
    'Content-Type': 'application/json',
    "Accept": 'application/json'
  }
}
https.get('https://api.nasa.gov/planetary/apod?api_key=DEMO_KEY',writedOptions, (resp) => {
  let data = '';
  // A chunk of data has been recieved.
  resp.on('data', (chunk) => {
    data += chunk;
  });
  // The whole response has been received. Print out the result.
  resp.on('end', () => {
    console.log(JSON.parse(data).explanation);
  });
}).on("error", (err) => {
  console.log("Error: " + err.message);
});
If you try with copiedOptions, you will get the same error.
Searching in https://github.com/nodejs/node/tree/master and the stackTrace: _http_outgoing.js:472
at ClientRequest.setHeader (_http_outgoing.js:472:3)
I founded this:
const tokenRegExp = /^[\^_`a-zA-Z\-0-9!#$%&'*+.|~]+$/;
/**
 * Verifies that the given val is a valid HTTP token
 * per the rules defined in RFC 7230
 * See https://www.rfc-editor.org/rfc/rfc7230#section-3.2.6
 */
function checkIsHttpToken(val) {
  return tokenRegExp.test(val);
}
That regex ensure that header name only has allowed tokens or chars according to https://www.rfc-editor.org/rfc/rfc7230#section-3.2.6
Maybe a earlier validation in nodejs core could help:
You have a not allowed char in your header name!
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