I would recommend this (just found via search):
If you want a command-line solution, you can use the ImageMagick convert
utility:
convert input.png -transparent red output.png
Paint.net is a free photo-editing tool that allows for transparent backgrounds. There is a simple example on YouTube http://www.youtube.com/watch?v=cdFpS-AvNCE. If you are still on Windows XP SP2 and that's an issue, I would first recommend doing the free service pack upgrade. But if that is not an option there are older versions of Paint.net that you could download and try.
Quick solution without downloading anything is to use online editors that has "Magic Wand Tool".
For Photoshop you need to download Photoshop portable.... Load image e press "w" click in image e suave as png or gif....
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