Although here https://www.google.com/design/icons/ contains an "exit to app" icon, I can't find it in its android library.
To embed Google Icons in your HTML web pages you have to add the link of material-icons font library in the <head> section of your HTML file and then add the class material-icons in the <i> or <span> tag of the <body> section along with the name of the icon.
exit_to_app is now available on material.io
Currently (2015-04-13) there is no icon for sign-in/sign-out, there is an open issue requesting it.
To solve this problem, in the meanwhile, I used the power_settings_new
icon .
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