It seems to be absent from the MS public symbol store, but it is also absent from the C:\Windows\System32 folder.
My symbol path is configured correctly, because I do get symbols for kernel32.dll and alike downloaded from the MS public symbol store and recognized by windbg.
It looks like the PDB is missing the MSI's. It used to be in MSI's for the earlier versions back to 4.1. But since going to 6.2 (part of Windows 7\8 SDK), the MSI's to not have the private PDBs.
Still looking...
FILE TABLE from Application Verifier x64 External Package-x64_en-us.msi
vfluapriv.dll 281656 6.2.9200.16384 1033 512 35
vfluapriv.dll 242776 6.2.9200.16384 1033 512 25
catdc3acb184552e9eeac50269425274d3c.cat 9783 512 29
vfprintpthelper.dll 711320 6.2.9200.16384 1033 512 36
appverif.chm 657331 512 15
appverif.chm 657331 512 6
appverif.exe 173520 6.2.9200.16384 1033 512 9
appverif.exe 216816 6.2.9200.16384 1033 512 17
cuzzapi.dll 23072 6.2.9200.16384 1033 512 34
cuzzapi.dll 21448 6.2.9200.16384 1033 512 22
cat2d609858545493b503b24bd3328d8d2a.cat 8157 512 5
cat4c0b3f635c0903217a3535759b7ce85f.cat 7792 512 10
catb1033a9482d5307d3df8fcd97174719e.cat 9783 512 19
vfprintpthelper.dll 367392 6.2.9200.16384 1033 512 26
cat9070517e54c750dca5f4eaa025eb8057.cat 8136 512 14
vfntlmless.dll 40136 6.2.9200.16384 1033 512 27
vfntlmless.dll 45336 6.2.9200.16384 1033 512 37
vfbasics.dll 406848 6.2.9200.16384 1033 512 16
vfbasics.dll 353328 6.2.9200.16384 1033 512 8
vfcompat.dll 90480 6.2.9200.16384 1033 512 38
vfcompat.dll 87328 6.2.9200.16384 1033 512 21
vfcuzz.dll 48976 6.2.9200.16384 1033 512 30
vfcuzz.dll 52032 6.2.9200.16384 1033 512 23
vfnet.dll 105056 6.2.9200.16384 1033 512 33
vfnet.dll 81592 6.2.9200.16384 1033 512 20
vfnws.dll 83248 6.2.9200.16384 1033 512 31
vfnws.dll 61384 6.2.9200.16384 1033 512 24
vfprint.dll 433376 6.2.9200.16384 1033 512 32
vfprint.dll 306592 6.2.9200.16384 1033 512 28
vrfauto.dll 211064 6.2.9200.16384 1033 512 2
vrfauto.dll 167392 6.2.9200.16384 1033 512 12
vrfauto.h 112394 512 4
vrfauto.h 112394 512 13
vrfauto.idl 31344 512 3
vrfauto.idl 31344 512 11
vrfcore.dll 183568 6.2.9200.16384 1033 512 18
vrfcore.dll 164200 6.2.9200.16384 1033 512 7
cat0f5c9874ec8b03b3a2ef2148f76b34cf.cat 7792 512 1
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