If I want to convert a piece of string to UTF-16, say char * xmlbuffer, do I have to convert  the type to wchar_t * before encoding to UTF-16? And is char* type reqired before encoding to UTF-8? 
How is wchar_t, char related to UTF-8 or UTF-16 or UTF-32 or other transformation format?
Thanks in advance for help!
No, you don't have to change data types.
About wchar_t: the standard says that
Type wchar_t is a distinct type whose values can represent distinct codes for all members of the largest extended character set specified among the supported locales.
Unfortunately, it does not say what encoding wchar_t is supposed to have; this is implementation-dependent. So for example given 
auto s = L"foo";
you can make absolutely no assumption about what the value of the expression *s is.
However, you can use an std::string as an opaque sequence of bytes that represent text in any transformation format of your choice without issue. Just don't perform standard library string-related operations on it.
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