I have a structure of arrays StockInfo in Matlab. The fields of the structure  StockInfo are as follows:
StockInfo = 
      Name: {10x1 cell}
    Values: [10x6 double]
    Return: [10x1 double]
I need to sort StockInfo based on the field Return, so that each array in the struct is sorted accordingly. Any idea how to do it?
As I mentioned in the comment above, you question is unclear. I think you are confusing structures and structure arrays. This post might be of help.
That said, here is an example to show what I think you meant to do.
First I create a structure array with some random data:
% cell array of 10 names
names = arrayfun(@(k) randsample(['A':'Z' 'a':'z' '0':'9'],k), ...
    randi([5 10],[10 1]), 'UniformOutput',false);
% 10x6 matrix of values
values = rand(10,6);
% 10x1 vector of values
returns = randn(10,1);
% 10x1 structure array
StockInfo = struct('Name',names, 'Values',num2cell(values,2), ...
    'Return',num2cell(returns));
The created variable is a an array of structures:
>> StockInfo
StockInfo = 
10x1 struct array with fields:
    Name
    Values
    Return
where each element is a structure with the following fields:
>> StockInfo(1)
ans = 
      Name: 'Pr3N4LTEi'
    Values: [0.7342 0.1806 0.7458 0.8044 0.6838 0.1069]
    Return: -0.3818
Next can sort this struct array by the "return" field (each struct has a corresponding scalar value):
[~,ord] = sort([StockInfo.Return]);
StockInfo = StockInfo(ord);
The result is that the array is now sorted by the "return" values in ascending order:
>> [StockInfo.Return]
ans =
  Columns 1 through 8
   -0.3818    0.4289   -0.2991   -0.8999    0.6347    0.0675   -0.1871    0.2917
  Columns 9 through 10
    0.9877    0.3929
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