Json.Net typically serializes a Dictionary<k,v> into a collection;
"MyDict": {
  "Apples": {
    "Taste": 1341181398,
    "Title": "Granny Smith",
  },
  "Oranges": {
    "Taste": 9999999999,
    "Title": "Coxes Pippin",
  },
 }
Which is great. And from looking around on SO it seems to be what most people want. However, in this particular case, I want to serialize between my Dictionary<k,v> and the Array format instead;
"MyDict": [
    "k": "Apples",
    "v": {
        "Taste": 1341181398,
        "Title": "Granny Smith",
    }
  },
    "k:": "Oranges",
    "v:": {
        "Taste": 9999999999,
        "Title": "Coxes Pippin",
    }
  },
]
Is there an easy way to do this with my existing field type? Is there an attribute I can annotate for instance?
Another way to accomplish this is to use a custom ContractResolver.  That way you do not have to subclass Dictionary<K,V> nor apply a transform each time you serialize, as suggested in other answers.
The following resolver will cause ALL dictionaries to be serialized as an array of objects with "Key" and "Value" properties:
class DictionaryAsArrayResolver : DefaultContractResolver
{
    protected override JsonContract CreateContract(Type objectType)
    {
        if (objectType.GetInterfaces().Any(i => i == typeof(IDictionary) || 
           (i.IsGenericType && i.GetGenericTypeDefinition() == typeof(IDictionary<,>))))
        {
            return base.CreateArrayContract(objectType);
        }
        return base.CreateContract(objectType);
    }
}
To use the resolver, add it to your JsonSerializerSettings, then pass the settings to JsonConvert.SerializeObject() like this:
JsonSerializerSettings settings = new JsonSerializerSettings();
settings.ContractResolver = new DictionaryAsArrayResolver();
string json = JsonConvert.SerializeObject(obj, settings);
Here is a working demo.
Ah, it turns out this is as straightforward as I'd hoped. My Dictionary<k,v> is subclassed already and I found that I can annotate it with [JsonArrayAttribute]. That gives me exactly the format I need;
"MyDict": [
  {
    "Key": "Apples",
    "Value": {
        "Taste": 1341181398,
        "Title": "Granny Smith",
    }
  },
  {
    "Key:": "Oranges",
    "Value:": {
        "Taste": 9999999999,
        "Title": "Coxes Pippin",
    }
  },
]
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