I just try to start Electron app on Windows with Electron Quick Start .
How to fix this error when running Electron on PyCharm?
runnerw.exe: CreateProcess failed with error 193: %1 is not a valid Win32 application.
PS: I am running on Windows 10 x64
My Electron Configuration
My Error

Try to use \.bin\electron.cmd instead of \.bin\electron in Node interpreter configuration
Hope this help.
I had the same problem with Git in Intellij IDEA, when I change a path in settings on C:\Program Files\Git\cmd\git.exe - it works now! Thanks
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