I'm having an issue with PDO Prepared statements, where if you need to use the same bind variable multiple times, the query won't validate.
Example:
$params = array (
    ':status' => $status,
    ':userid' => $_SESSION['userid']
);
$stmt = $pdo->prepare ('
    INSERT INTO 
        tableName
        ( userId, status )
        VALUES
        ( :userid, ":status" )
        ON DUPLICATE KEY UPDATE
            status = ":status"
');
if ( ! $stmt->execute ( $params ))
{
    print_r( $stmt->errorInfo ());
}
EDIT: The values of the $params are:Array ( [:status] => PAID [:userid] => 111 )
EDIT 2:
I've noticed that instead of the original values, instead of userid, 0 is inserted, and instead of status an empty string is inserted.
Problem was the quotes around the :status. Removed quotes and all is good.
Your array keys don't need to contain a colon. The colon is purely for PDO to know that what follows is a named parameter.
$params = array (
    ':status' => $status,
    ':userid' => $_SESSION['userid']
);
should be
$params = array (
    'status' => $status,
    'userid' => $_SESSION['userid']
);
                        You're not calling the bindParam method anywhere, why? Just before you invoke execute, try adding
$stmt->bindParam(':userid', $_SESSION['userid'], PDO::PARAM_INT);
$stmt->bindParam(':status', $status, PDO::PARAM_STR);
And then just call $stmt->execute(); see how that works for you. Also turn your error messages up to full, and after instantiating your PDO instance, add this $db->setAttribute(PDO::ATTR_ERRMODE,PDO::ERRMODE_EXCEPTION); to ensure errors are always thrown. 
the docs are handy things
Works fine for me. E.g.
<?php
$pdo = new PDO('mysql:host=localhost;dbname=test;charset=utf8', 'localonly', 'localonly');
$pdo->setAttribute(PDO::ATTR_ERRMODE, PDO::ERRMODE_EXCEPTION);
setup($pdo);
echo 'client version: ', $pdo->getAttribute(PDO::ATTR_CLIENT_VERSION), "\n";
echo 'server version: ', $pdo->getAttribute(PDO::ATTR_SERVER_VERSION), "\n";
echo "before:\n";
foreach( $pdo->query('SELECT * FROM tmpTableName', PDO::FETCH_ASSOC) as $row ) {
    echo join(', ', $row), "\n";
}
$status = 1;
$_SESSION['userid'] = 'foo';
$params = array (
    'status' => $status,
    'userid' => $_SESSION['userid'],
);
$stmt = $pdo->prepare ('
    INSERT INTO 
        tmpTableName
        (userId, status)
    VALUES
        (:userid, :status)
    ON DUPLICATE KEY UPDATE
        status = :status
');
if ( ! $stmt->execute ( $params ))
{
    print_r( $stmt->errorInfo ());
}
echo "after:\n";
foreach( $pdo->query('SELECT * FROM tmpTableName', PDO::FETCH_ASSOC) as $row ) {
    echo join(', ', $row), "\n";
}
function setup($pdo) {
    $pdo->exec('
        CREATE TEMPORARY TABLE tmpTableName (
            userId varchar(32),
            status int,
            unique key(userId)
        )
    ');
    $pdo->exec("INSERT INTO tmpTableName (userId,status) VALUES ('foo', 0)");
    $pdo->exec("INSERT INTO tmpTableName (userId,status) VALUES ('bar', 0)");
}
prints
client version: mysqlnd 5.0.10 - 20111026 - $Id: b0b3b15c693b7f6aeb3aa66b646fee339f175e39 $
server version: 5.5.25a
before:
foo, 0
bar, 0
after:
foo, 1
bar, 0
on my machine
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