i have a two dataframes as:
df = pd.DataFrame({'America':["Ohio","Utah","New York"],
                   'Italy':["Rome","Milan","Venice"],
                   'Germany':["Berlin","Munich","Jena"]});
df2 = pd.DataFrame({'Cities':["Rome", "New York", "Munich"],
                   'Country':["na","na","na"]})
i want to itirate on df2 "Cities" column to find the cities on my (df) and append the country of the city (df column names) to the df2 country column
Use melt with map by dictionary:
df1 = df.melt()
print (df1)
  variable     value
0  America      Ohio
1  America      Utah
2  America  New York
3    Italy      Rome
4    Italy     Milan
5    Italy    Venice
6  Germany    Berlin
7  Germany    Munich
8  Germany      Jena
df2['Country'] = df2['Cities'].map(dict(zip(df1['value'], df1['variable'])))
#alternative, thanks @Sandeep Kadapa 
#df2['Country'] = df2['Cities'].map(df1.set_index('value')['variable'])
print (df2)
     Cities  Country
0      Rome    Italy
1  New York  America
2    Munich  Germany
                        After melting and renaming the first dataframe:
df1 = df.melt().rename(columns={'variable': 'Country', 'value': 'Cities'})
the solution is a simple merge:
df2 = df2[['Cities']].merge(df1, on='Cities')
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