My team uses a Git team project with TFS 2013 Update 4. Email notifications are sent out as expected when a pull request is created or a branch under review is updated. However, notifications aren't sent when a comment is added to the pull request - is it possible to enable that?
Follow a pull request To track the progress of a single pull request, choose the actions icon for the pull request, and select the Follow option. This signals the system to notify you when changes are made to the PR.
On the pull request, click Files changed. Hover over the line of code where you'd like to add a comment, and click the blue comment icon. To add a comment on multiple lines, click and drag to select the range of lines, then click the blue comment icon. In the comment field, type your comment.
To resolve a comment without replying, select Resolve under the comment. To reply to the comment, type your response in the Write a reply field, and select Reply. To reply to and resolve the comment, type your response in the Write a reply field, and select Reply & resolve.
I don't believe that is currently possible, but it is a good idea. You should head over to http://visualstudio.uservoice.com and add it.
As of the 5/11/2017 release, users now get notifications for comments on PRs they create or have participated in.
https://docs.microsoft.com/en-us/vsts/release-notes/2017/may-11-team-services#default-notifications-for-pr-comments
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