I can't find any information relating to this on Amazon's site, but is this possible?
Sure you can,
I am using PHP PostgreSQL to query AWS Redshift
For those who are looking for examples:
$connection = new PDO(
    'pgsql:dbname=<db_name>;host=<redshift_cluster_host>;port=5439',
    '<master_user_name>', 
    '<master_user_password>'
);
$statement = $connection->prepare('<your_query>');
$statement->execute();
$result = $statement->fetch();
Also, ensure you configured your cluster security groups correctly (under Security tab in the AWS Redshift admin).
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