Is it possible to develop a windows application using PHP that should access the information of the OS and other features like writing the content into MS WORD, Excel etc.
It is possible through: http://php.net/manual/en/ref.com.php
But you won't find much help nor is it efficient to do.
You'd be better of using any of the .NET languages. I'd personally recommend C#.
However for your mentioned use-cases there are libraries like PHPExcel and PHP also provides drivers for many popular databases.
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