I am using
imageData = UIImagePNGRepresentation(imgvw.image);  
and while posting
[dic setObject:imagedata forKey:@"image"]; 
after
NSData *data = [NSJSONSerialization dataWithJSONObject:dic options:NSJSONWritingPrettyPrinted error:&theError];
now app is crashing Terminating app due to uncaught exception 'NSInvalidArgumentException', reason: 'Invalid type in JSON write (NSConcreteMutableData)
You need to convert your UIImage to NSData and then convert that NSData to a NSString which will be base64 string representation of your data.
Once you get the NSString* from NSData*, you can add it to your dictionary at key @"image"
To convert NSData to a base64 type NSString* refer to the following link: How do I do base64 encoding on iphone-sdk?
In a more pseudo-way the process will look like this
UIImage *my_image; //your image handle
NSData *data_of_my_image = UIImagePNGRepresentation(my_image);
NSString *base64StringOf_my_image = [data_of_my_image convertToBase64String];
//now you can add it to your dictionary
NSMutableDictionary *dict = [NSMutableDictionary dictionary];
[dict setObject:base64StringOf_my_image forKey:@"image"];
if ([NSJSONSerialization isValidJSONObject:dict]) //perform a check
{
        NSLog(@"valid object for JSON");
        NSError *error = nil;
        NSData *jsonData = [NSJSONSerialization dataWithJSONObject:dict options:NSJSONWritingPrettyPrinted error:&error];
        if (error!=nil) {
            NSLog(@"Error creating JSON Data = %@",error);
        }
        else{
            NSLog(@"JSON Data created successfully.");
        }
}
else{
        NSLog(@"not a valid object for JSON");
    }
                        Try this
NSData *imageData  = [UIImageJPEGRepresentation(self.photoImageView.image, compression)  dataUsingEncoding:NSUTF8StringEncoding];
const unsigned char *bytes = [imageData bytes]; 
NSUInteger length = [imageData length];
NSMutableArray *byteArray = [NSMutableArray array];
for (NSUInteger i = 0; i length; i++)
{
    [byteArray addObject:[NSNumber numberWithUnsignedChar:bytes[i]]];
}
NSDictionary *dictJson = [NSDictionary dictionaryWithObjectsAndKeys:
              byteArray, @"photo",
              nil];
NSData *jsonData = [NSJSONSerialization dataWithJSONObject:dictJson options:0 error:NULL];
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