I tried the below code to get the value of a particular node, but while loading the xml this exception is thrown:
Exception:
Data at the root level is invalid. Line 1, position 1.
XML
<?xml version="1.0"?> <Data xmlns:xsd="http://www.w3.org/2001/XMLSchema" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance">      <Date>11-07-2013</Date>      <Start_Time>PM 01:37:11</Start_Time>      <End_Time>PM 01:37:14</End_Time>      <Total_Time>00:00:03</Total_Time>      <Interval_Time/>     <Worked_Time>00:00:03</Worked_Time>      <Short_Fall>08:29:57</Short_Fall>      <Gain_Time>00:00:00</Gain_Time>  </Data>   C#:
XmlDocument xml = new XmlDocument(); filePath = @"D:\Work_Time_Calculator\10-07-2013.xml"; xml.LoadXml(filePath);  // Exception occurs here  XmlNode node = xml.SelectSingleNode("/Data[@*]/Short_Fall"); string id = node["Short_Fall"].InnerText;   Modified Code
C#:
XmlDocument xml = new XmlDocument(); filePath = @"D:\Work_Time_Calculator\10-07-2013.xml"; xml.Load(filePath);   XmlNode node = xml.SelectSingleNode("/Data[@*]/Short_Fall"); string id = node["Short_Fall"].InnerText; // Exception occurs here ("Object reference not set to an instance of an object.") 
                The problem in your code is xml.LoadXml(filePath);
LoadXmlmethod take parameter as xml data not the xml file path
Try this code
   string xmlFile = File.ReadAllText(@"D:\Work_Time_Calculator\10-07-2013.xml");                 XmlDocument xmldoc = new XmlDocument();                 xmldoc.LoadXml(xmlFile);                 XmlNodeList nodeList = xmldoc.GetElementsByTagName("Short_Fall");                 string Short_Fall=string.Empty;                 foreach (XmlNode node in nodeList)                 {                     Short_Fall = node.InnerText;                 }   Edit
Seeing the last edit of your question i found the solution,
Just replace the below 2 lines
XmlNode node = xml.SelectSingleNode("/Data[@*]/Short_Fall"); string id = node["Short_Fall"].InnerText; // Exception occurs here ("Object reference not set to an instance of an object.")   with
string id = xml.SelectSingleNode("Data/Short_Fall").InnerText;   It should solve your problem or you can use the solution i provided earlier.
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