You could use http://builtwith.com to figure out which server and programming language was used. For example it told me that SO uses IIS7, google analytics, html4 and utf8.
If you want to know the framework...well that will probably not be possible just from looking at the site. Why don't you write them an email? ;)
There are all sorts of things you can look out for, but it doesn't really give you any certainty as to the technology behind a site. In general, information like that is something people will want to hide, as the more information that is exposed the easier it might be for malicious parties to identify security vulnerabilities or denial of service holes.
If I was interested I'd probably look, in no particular order, at:
Incidentally, the tools mentioned in other answers are only looking at some of the above properties of the site for you, albeit automatically, and slightly quicker. :)
I use 1 plug in for Firefox that gives me the IP and country for the hosting website and it's Web Server name called Domain Details, and for javascript framework I use WTFramework
I still need to wonder what script it was written on, but it is a start :)
Hope it helps.
P.S. the output will be something like this:
alt text http://img88.imageshack.us/img88/2505/200812282328ha0.png
URLs can give a lot of clues, especially with Content Management Systems.
For example "http://abcxyz.com/node/46" looks a lot like Drupal.
Also many frameworks have standard JavaScript and CSS files they use.
Some people might even deliberately obscure the technology they use. After all, it wouldn't take me long to tweak apache so that ".asp" actually ran perl scripts and put "powered by Microsoft IIS" into my footer despite the fact I used MySQL.
That way you'd spend all your time trying to hack my site using vulnerabilities it doesn't actually have.
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