How can I transform the following XML into a List<string> or String[]:
<Ids>
  <id>1</id>
  <id>2</id>
</Ids>
                It sounds like you're more after just parsing rather than full XML serialization/deserialization. If you can use LINQ to XML, this is pretty easy:
using System;
using System.Linq;
using System.Xml.Linq;
public class Test
{
    static void Main()
    {
        string xml = "<Ids><id>1</id><id>2</id></Ids>";
        XDocument doc = XDocument.Parse(xml);
        var list = doc.Root.Elements("id")
                           .Select(element => element.Value)
                           .ToList();
        foreach (string value in list)
        {
            Console.WriteLine(value);
        }
    }
}
In fact the call to Elements could omit the argument as there are only id elements, but I thought I'd demonstrate how to specify which elements you want.
Likewise I'd normally not bother calling ToList unless I really needed a List<string> - without it, the result is IEnumerable<string> which is fine if you're just iterating over it once. To create an array instead, use ToArray.
Here is a way using XmlDocument :
// A string containing the XML data
string xml = "<Ids><id>1</id><id>2</id></Ids>";
// The list you want to fill
ArrayList list = new ArrayList();
XmlDocument doc = new XmlDocument();
// Loading from a XML string (use Load() for file)
doc.LoadXml(xml); 
// Selecting node using XPath syntax
XmlNodeList idNodes = doc.SelectNodes("Ids/id");
// Filling the list
foreach (XmlNode node in idNodes)
    list.Add(node.InnerText);
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