I'm using below code to display Image & Name of webisites form database.
<fieldset>  
    <h1>A</h1>          
    <ul>
        <?php foreach ($records as $key) { ?>
        <li class="siteli"> <a href="#" class="add">        
            <div id="site-icon"><img src="<?php echo $key->site_img; ?>" width="16" height=""></div>
            <p id="text-site"> <?php echo $key->site_name; ?></p>
        </li>
        <?php } ?>
    </ul>
</fieldset>
Now I'm trying to group this results alphabetically by adding A, B, C etc as title.
Example,
A    
Amazon     
Aol    
Aol Mail
B    
Bing     
Bogger
                You can use array sorting to sort the array. In your case I would choose sort()
Now to show the links with a preceding Letter I would use:
<?php
$records = ['Aaaaa', 'Aaaa2', 'bbb', 'bbb2', 'Dddd'];
$lastChar = '';
sort($records, SORT_STRING | SORT_FLAG_CASE); //the flags are needed. Without the `Ddd` will come before `bbb`.
//Available from version 5.4. If you have an earlier version (4+) you can try natcasesort()
foreach($records as $val) {
  $char = $val[0]; //first char
  if ($char !== $lastChar) {
    if ($lastChar !== '')
      echo '<br>';
    echo strtoupper($char).'<br>'; //print A / B / C etc
    $lastChar = $char;
  }
 echo $val.'<br>';
}
?>
This will output something like
A
Aaaa2
Aaaaa
B
bbb
bbb2
D
Dddd
Notice that the C is missing, because there are no words starting with C.
This is a modification of @Hugo Delsing's answer.
I needed to be able to group my brands together like this, but one bug in the code was the fact that if I had say iForce Nutrition and Inner Armour it would group these into two separate groups because of the letter case.
Changes I Made
Because it was fully alphabetical, it was only going by first letter I changes SORT_STRING to SORT_NATURAL
Changed: if ($char !== $lastChar) to if (strtolower($char) !== strtolower($lastChar))
<?php
$records = ['FinaFlex', 'iForce Nutrition', 'Inner Armour', 'Dymatize', 'Ultimate    Nutrition'];
$lastChar = '';
sort($records, SORT_NATURAL | SORT_FLAG_CASE); //Allows for a full comparison and will alphabetize correctly.
foreach($records as $val) {
 $char = $val[0]; //first char
  if (strtolower($char) !== strtolower($lastChar)) {
    if ($lastChar !== '')
     echo '<br>';
     echo strtoupper($char).'<br>'; //print A / B / C etc
     $lastChar = $char;
    }
    echo $val.'<br>';
  }
?>
The final output will be like this
D
Dymatize
F
FinaFlex
I
iForce Nutrition
Inner Armour
U
Ultimate Nutrition
I hope this helps everyone, and a big thank you to Hugo for providing the code that got me exactly where I needed to be.
You can see my example here https://hyperionsupps.com/brand-index
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