Open up your file using regular old vanilla Notepad that comes with Windows. It will show you the encoding of the file when you click "Save As...". Whatever the default-selected encoding is, that is what your current encoding is for the file.
Open the file with Notepad++ and will see on the right down corner the encoding table name. And in the menu encoding you can change the encoding table and save the file.
Open the file in Notepad. Click 'Save As...'. In the 'Encoding:' combo box you will see the current file format. Yes, I opened the file in notepad and selected the UTF-8 format and saved it.
The evaluated encoding of the open file will display on the bottom bar, far right side. The encodings supported can be seen by going to Settings -> Preferences -> New Document/Default Directory and looking in the drop down.
Open up your file using regular old vanilla Notepad that comes with Windows.
It will show you the encoding of the file when you click "Save As...".
It'll look like this:

Whatever the default-selected encoding is, that is what your current encoding is for the file.
If it is UTF-8, you can change it to ANSI and click save to change the encoding (or visa-versa).
I realize there are many different types of encoding, but this was all I needed when I was informed our export files were in UTF-8 and they required ANSI. It was a onetime export, so Notepad fit the bill for me.
FYI: From my understanding I think "Unicode" (as listed in Notepad) is a misnomer for UTF-16.
More here on Notepad's "Unicode" option: Windows 7 - UTF-8 and Unicdoe
If you have "git" or "Cygwin" on your Windows Machine, then go to the folder where your file is present and execute the command:
file *
This will give you the encoding details of all the files in that folder.
The (Linux) command-line tool 'file' is available on Windows via GnuWin32:
http://gnuwin32.sourceforge.net/packages/file.htm
If you have git installed, it's located in C:\Program Files\git\usr\bin.
Example:
C:\Users\SH\Downloads\SquareRoot>file *
_UpgradeReport_Files; directory
Debug; directory
duration.h; ASCII C++ program text, with CRLF line terminators
ipch; directory
main.cpp; ASCII C program text, with CRLF line terminators
Precision.txt; ASCII text, with CRLF line terminators
Release; directory
Speed.txt; ASCII text, with CRLF line terminators
SquareRoot.sdf; data
SquareRoot.sln; UTF-8 Unicode (with BOM) text, with CRLF line terminators
SquareRoot.sln.docstates.suo; PCX ver. 2.5 image data
SquareRoot.suo; CDF V2 Document, corrupt: Cannot read summary info
SquareRoot.vcproj; XML document text
SquareRoot.vcxproj; XML document text
SquareRoot.vcxproj.filters; XML document text
SquareRoot.vcxproj.user; XML document text
squarerootmethods.h; ASCII C program text, with CRLF line terminators
UpgradeLog.XML; XML document text
C:\Users\SH\Downloads\SquareRoot>file --mime-encoding *
_UpgradeReport_Files; binary
Debug; binary
duration.h; us-ascii
ipch; binary
main.cpp; us-ascii
Precision.txt; us-ascii
Release; binary
Speed.txt; us-ascii
SquareRoot.sdf; binary
SquareRoot.sln; utf-8
SquareRoot.sln.docstates.suo; binary
SquareRoot.suo; CDF V2 Document, corrupt: Cannot read summary infobinary
SquareRoot.vcproj; us-ascii
SquareRoot.vcxproj; utf-8
SquareRoot.vcxproj.filters; utf-8
SquareRoot.vcxproj.user; utf-8
squarerootmethods.h; us-ascii
UpgradeLog.XML; us-ascii
Another tool that I found useful: https://archive.codeplex.com/?p=encodingchecker EXE can be found here
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