have a df with values
df:
165  156  1    test    greater 56gsa
-------------------------------------
spin 201  2    normal  lesser  12asgs
pine 202  3    fast    greater 5sasgs
required output:
0     1   2     3        4       5
-------------------------------------
165  156  1    test    greater 56gsa
spin 201  2    normal  lesser  12asgs
pine 202  3    fast    greater 5sasgs
                If DataFrame is created from file then header=None parameter is your friend:
df = pd.read_csv(file, header=None)
If not then convert column to one row DataFrame and DataFrame.append to original data:
df = df.columns.to_frame().T.append(df, ignore_index=True)
df.columns = range(len(df.columns))
print (df)
      0    1  2       3        4       5
0   165  156  1    test  greater   56gsa
1  spin  201  2  normal   lesser  12asgs
2  pine  202  3    fast  greater  5sasgs
                        Try using reset_index:
print(df.T.reset_index().T)
For resetting and dropping original columns:
print(df.T.reset_index(drop=True).T)
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