How to set specific color to active cell when creating XLS document in PHPExcel?
$sheet->getStyle('A1')->applyFromArray(
    array(
        'fill' => array(
            'type' => PHPExcel_Style_Fill::FILL_SOLID,
            'color' => array('rgb' => 'FF0000')
        )
    )
);
Source: http://bayu.freelancer.web.id/2010/07/16/phpexcel-advanced-read-write-excel-made-simple/
function cellColor($cells,$color){
    global $objPHPExcel;
    $objPHPExcel->getActiveSheet()->getStyle($cells)->getFill()->applyFromArray(array(
        'type' => PHPExcel_Style_Fill::FILL_SOLID,
        'startcolor' => array(
             'rgb' => $color
        )
    ));
}
cellColor('B5', 'F28A8C');
cellColor('G5', 'F28A8C');
cellColor('A7:I7', 'F28A8C');
cellColor('A17:I17', 'F28A8C');
cellColor('A30:Z30', 'F28A8C');

This code should work for you:
 $PHPExcel->getActiveSheet()
        ->getStyle('A1')
        ->getFill()
        ->setFillType(PHPExcel_Style_Fill::FILL_SOLID)
        ->getStartColor()
        ->setRGB('FF0000')
But if you bother using this over and over again, I recommend using applyFromArray.
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