When I change or add something to my app's plist, a minimal plist appears on the left side of Xcode. I can open this small plist as source code. My question is: how can I view the base or entire app plist located in the Info tab under the "Custom macOS Application Target Properties" section as source code?

You need to go in the project folder directly, not in xcode, then click on info.plist. This will now make the file visible in xcode. And you can right click and select edit as source code now.
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