Is it somehow possible to float (overlapping with align) children in a panel in wpf. I have 4 Buttons that overlap each other. They need to align to the left, right, top and bottom and grow with the parent container. Please take a look on the image for more information.

How about this?
<Grid>
<Grid>
<Grid.RowDefinitions>
<RowDefinition Height="1*"/>
<RowDefinition Height="2*"/>
<RowDefinition Height="1*"/>
</Grid.RowDefinitions>
<Grid.ColumnDefinitions>
<ColumnDefinition/>
<ColumnDefinition/>
</Grid.ColumnDefinitions>
<Button Grid.Row="1" Grid.Column="0" Content="Left"/>
<Button Grid.Row="1" Grid.Column="1" Content="Right"/>
</Grid>
<Grid>
<Grid.RowDefinitions>
<RowDefinition/>
<RowDefinition />
</Grid.RowDefinitions>
<Grid.ColumnDefinitions>
<ColumnDefinition Width="1*"/>
<ColumnDefinition Width="2*"/>
<ColumnDefinition Width="1*"/>
</Grid.ColumnDefinitions>
<Button Grid.Row="0" Grid.Column="1" Content="Top"/>
<Button Grid.Row="1" Grid.Column="1" Content="Bottom"/>
</Grid>
</Grid>
which results in

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