Which data base is most appropriate for storing key/value pairs? And the database should support mobile enviroment or devices.
Applications are intened to run on windows mobile and windows phone
There is really no simple answer to this with so little information. Take a google at "No SQL" or "Document Databases" - should find you what you need.
If you are after WP7 there are some good suggestions here http://nosql-database.org/
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