My developer has added a new app in iTunes Connect for me, but the default language is "UK English". I've now also added the generic "English".
I now want to delete "UK English", but I can't because it's the default. I can only delete the generic English. How do I change which language is the default?
Open "System Preferences" Open "Language & Region". There is list of "Preferred language" on the left panel. Click on the button "+" under the list and add English language as primary.
According to App Store Docs :
My Apps Prepare for Submission or Waiting for Review)
Use English (U.S.) from each device screenshotsSave if your app is already available on app store you will need to upload your screenshots and fill all fields for this language and submit this version to review, then finish the next steps on another update after approval of this version
App information --> Primary language 
Save EDIT: Since September 2014 this answer out-of-date as the iTunes Connect interface has changed
I discovered that there is a way to change the default language after all:
That's it!
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